March 18, 2011 | FJ Gaylor Is It Graham’s Law? Students in a chemistry lecture hall learn about the effusion of gases. Photo by FJ Gaylor Students in a chemistry lecture hall learn about the effusion of gases. Graham's law of effusion was formulated by Scottish physical chemist Thomas Graham, who found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the mass of its particles. Photo by FJ Gaylor